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The historians and geologists think that the group of the Pisan Mountains is one of the mountainous formations most ancient of Italy. The clues most remote of that are "the Scisti of S. Lorenzo ", ( coal permo age, about 280 million of years ) that are on the Cotrozzi mt., formed during the said geological era Paleozoic or primary ( stones appearing also in the core of the Apuane Alps ). In particular in the Scisti of S. Lorenzo a rich fossil flora has been found. The type of vegetation, the amount and the level of his development makes think of a climate decidedly tropical, hot damp, what supported an development of flourishing forests with floras prevalently swampy (Lycopodial and Equisetum) in wet environments and lagoon. Subsequently the mountains became one among the few "atolls" in the pliocenic period, when the central Italy was covered, for most from water. Their formation would have happened, with a first lifting phase followed by a second sinking phase, this is the because of some there lean on the plain. Part of mountains, above all the piedmont South-west part, is constituted of calcareous roccie, fact that it has allowed the formation of cavities become caverns in various cases more or not extensive.  To notice than for the geological science exists a rock, called Verrucana which has really taken the name from the Verruca mountain that one finds in the Pisan mt. (in top rises the ruin of an ancient fortress) and that it distinguishes him for his presence.
The mountain's anthropic presence is begun in much remote epoches in fact, thanks to the first spelaeological explorations of the cave led by the half of the eight hundred, paleontologic and paleo-ethnologic fossil of the superior Paleolith have been found, ever since however the biggest frequentation, has had herself above all to South, in the Calci zone, before the Etruscan ones, from apuani or Ligurians, because the valley was supplied with all one what of better the nature could still offer: shelter, water, game, woods. Later, after the Etruscan, came Romans, what as precedents used the calcareous stone of the Pisan Mountains to do lime, and being near of Arno and also of the sea at that epoch, to deal in it in the Mediterranean sea, as we know from the findings of the Roman ships under the station trains of Pisa S. Rossore. To the dawnings of the Christian cult, the zone was identified as ideal place for the retirement and the prayer. This gave the start to the building of various churches, orators, parishes, allowing the development of the main country: Calci.